Current-rate flash sintering of gadolinium doped ceria: Microstructure and Defect generation
نویسندگان
چکیده
منابع مشابه
Improvement of ionic conductivity of gadolinium doped ceria electrolyte with nano CuO sintering aid
Gadanium doped cerium oxide ceramic (GDC) is widely used as solid electrolytes in solid oxide fuel cells because of its high oxygen ion conductivity. In this study, the effect of addition of nano CuO as a sintering aid on the properties of GDC electrolyte were investigated. For this purpose, 0.2, 0.5, and 1% mole of nano Cuo was added to GDC ceramics, which was synthesized by the solid-state me...
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The nano-domain, with short-range ordered structure, has been widely observed in rare-earth-doped ceria. Atomistic simulation has been employed to investigate the ordering structure of the nano-domain, as a result of aggregation and segregation of dopant cations and the associated oxygen vacancies in gadolinium-doped ceria. It is found that the binding energy of defect cluster increases as a fu...
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Flash sintering as a new sintering method for sintering of ceramic materials has been studied and effect of various parameter such as flash current density, time of flash and contact paste on properties of flash sintered 8YSZ samples has been investigated. Results showed it is possible to achieve high density in shorter time and lower temperature than conventional sintering methods. Samples cou...
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This study proposes a seed/template-free method that affords high-purity semiconducting nanowires from nanoclusters, which act as basic building blocks for nanomaterials, under supercritical CO2 fluid. Polycrystalline nanowires of Gd-doped ceria (Gd-CeO2) were formed by CO2-mediated non-oriented attachment of the nanoclusters resulting from the dissociation of single-crystalline aggregates. The...
متن کاملOptimization of ionic conductivity in doped ceria.
Oxides with the cubic fluorite structure, e.g., ceria (CeO2), are known to be good solid electrolytes when they are doped with cations of lower valence than the host cations. The high ionic conductivity of doped ceria makes it an attractive electrolyte for solid oxide fuel cells, whose prospects as an environmentally friendly power source are very promising. In these electrolytes, the current i...
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ژورنال
عنوان ژورنال: Acta Materialia
سال: 2020
ISSN: 1359-6454
DOI: 10.1016/j.actamat.2020.02.036